Table 1: PV of oleic acid oxidation by singlet oxygen in different condition a.
|
Entry |
Condition |
PV |
|
1 |
Oleic acid+ Acetonitrile + light + air |
trace |
|
2 |
Oleic acid+ Acetonitrile +H2TPP+air |
trace |
|
3 |
Oleic acid+ Acetonitrile +H2TPP+light+air |
101.67 |
|
4 |
Oleic acid+ Acetonitrile + MgTPP +light+air |
70.39 |
|
5 |
Oleic acid+ Acetonitrile + ZnTPP +light+air |
79.33 |
|
6 |
Oleic acid+ Acetonitrile +H2TPP+light+air+DABCO |
trace |
|
7 |
Oleic acid+DMSO+ H2TPP+ light+air |
27.93 |
|
8 |
Oleic acid+Ethanol+H2TPP+ light+air |
89.38 |
|
9b |
Oleic acid+ O2·- |
trace |
a Oleic acid (4.6×10-3 M), 5cc solvent, photosensitizer (1×10-3 M), air (1atm) and 288 power LED lamps, 1 W, 2.3 V (59660 LUX). b O2•– was prepared by dissolving K2O in dried DMSO.